电池动态电化学阻抗谱的无源检测方法研究
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1.重庆大学电气工程学院输变电装备技术全国重点实验室重庆400044; 2.国网重庆市电力公司 电力科学研究院重庆401121

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TH89TM93

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国家电网有限公司总部管理科技项目(5108-202218280A-2-314-XG)资助


Study of passive detection methods for dynamic electrochemical impedance spectroscopy of batteries
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1.School of Electrical Engineering, Chongqing University State Key Laboratory of Power Transmission and Transformation Equipment Technology, Chongqing 400044, China; 2.Electric Power Scientific Research Institute, State Grid Chongqing Electric Power Company, Chongqing 401121, China

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    摘要:

    电化学阻抗谱(EIS)作为一种无损检测方法,被广泛用于研究电池内部电化学过程,在充放电过程中进行动态阻抗谱(DEIS)的检测更能够真实反映电池的健康状态。目前,DEIS检测主要依赖于电化学工作站,由于受限于测试仪器的激励源功率,多停留在实验室电芯的检测和研究中,尚无法应用于大功率模组电池的现场检测。提出一种无需额外施加激励的电池DEIS检测方法,设计了适用于电芯及模组的静态、动态EIS检测系统。以磷酸铁锂电池和标准RC阻容盒为检测对象,对比分析了传统电化学工作站和本文提出检测系统的测试效果。结果表明,该方案不但测试误差小、稳定性好,且具有不受外加激励源功率限制的显著优势,在未来大规模储能电池的运行状态评估中具有良好的应用前景。

    Abstract:

    Electrochemical impedance spectroscopy (EIS), as a non-destructive testing method, is widely used to study the internal electrochemical processes of batteries. Dynamic impedance spectroscopy (DEIS) testing during charging and discharging is more capable of truly reflecting the health status of batteries. At present, DEIS detection mainly relies on electrochemical workstations. Due to the limitation of the excitation source power of the test instrument, it mostly stays in the detection and research of laboratory cells, and cannot be applied to the field detection of high-power module batteries yet. In this article, we propose a battery DEIS detection method without additional excitation, and design a static and dynamic EIS detection system applicable to battery cells and modules. Taking lithium iron phosphate batteries and standard RC resistor cells as testing objects, the proposed testing effects of traditional electrochemical workstations and the testing system are compared and analyzed. The results show that the proposed scheme not only has small testing error and good stability, but also has the significant advantage of not being limited by the power of the external excitation source, which has a good application prospect in the future evaluation of the operating state of large-scale energy storage batteries.

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吴绪,杨丽君,肖滟琳,王平,李思全.电池动态电化学阻抗谱的无源检测方法研究[J].仪器仪表学报,2024,45(12):107-117

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  • 在线发布日期: 2025-03-04
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